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Micro-imaging of transient guest profiles in nanoporous host systems of cylindrical symmetry

机译:圆柱对称纳米多孔宿主系统中瞬态客体轮廓的微成像

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摘要

Nanoporous host materials giving rise to transient guest profiles of cylindrical symmetry during molecular uptake and release are shown to provide particularly advantageous conditions for the study of guest diffusion by micro-imaging. Considering zeolites of structure type DDR (Deca-dodecasil 3R) as a host system and short-chain length hydrocarbons as guest molecules, the benefits thus attainable in micro-imaging studies using interference microscopy are shown to include the determination of transient concentration profiles with improved accuracy, the option to overcome the disturbing impact of surface imperfections, and easy access to concentration-dependent diffusivities.
机译:纳米多孔主体材料在分子的吸收和释放过程中产生了圆柱对称的瞬时客体轮廓,显示出为通过微成像研究客体扩散提供特别有利的条件。将DDR型结构的分子筛(Deca-dodecasil 3R)用作主体系统,将短链长度的烃作为客体分子,使用干涉显微镜的显微成像研究因此获得的好处包括确定瞬态浓度曲线并进行改进精度,克服表面缺陷的令人不安的影响的选项,以及易于获得浓度依赖性扩散系数的方法。

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